Green has a calming effect on one's mood, so maybe a green desk lamp neutralizes the effects of a stressful day at your work desk. Just guessing.
Yes they will work if they fit the fixture.... They will only draw the 20 watts they need to operate, so No, you will not blow the 20W lamps.... Ensure however that the lamps you will be using are rated for 220 volt operation... I am guessing you are...
At Target I got a clip-on lamp for $2. Holds a 40-watt bulb and works great. And it's cute. Target, Wal-Mart, K-Mart have a lot of cheap lamps.. especially for dorms and back-to-school supplies.